The question is “how many 32 fit in 421?”, so it is a division. Write the mixed number as a fraction: 421=29.
To divide by 32, multiply by its reciprocal, 23:
You can make 6 full servings. What is left is 43 of a serving, that is 43×32=21 cup.
Check: 6×32=4 cups, plus the 21 cup left over, makes 421 cups.